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New types of membranes for electrolyzer hydrogen - oxygen
Hýbl, Jiří ; Sedlaříková, Marie (referee) ; Kunovjánek, Miroslav (advisor)
This work deals with the production of hydrogen and oxygen by electrolysis. Aims of this thesis are to measure different types of membranes and choose the best for use in elektrolyzer for hydrogen and oxygen production. Properties of membranes were tested in the laboratory electrolyzer in the short and long operation. The emerging gases from elektrolyzer were also tested on a gas chromatograph to determine the purity of produced hydrogen. At the same time are also tested different concentrations of KOH elektrolyte and the effect of concentrations on efficiency of electrolyzer.
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The design of electrochemical sensor with integrated potentiostat chip
Uhlár, Martin ; Novotný, Marek (referee) ; Adámek, Martin (advisor)
The research on electrochemical sensor applications in combination with application-defined electronic circuits is a very fast developing field of modern sensorics. Device designing of unique integrated systems with specific properties and parameters is now becoming the everyday practice for producers of devices based on the latest technology progress in microelectronics. In the process of realization of a new device type, the main objective consists in increasing the possibility of detecting very low concentrations of heavy metals in the given chemical solution, extending the signal-to-noise ratio, and measuring the potential of a sensor. The general aim of this Master’s thesis is to design the topology of a sensor based on the thick film technology, to materialize the sensor, and to make experimental measurement using the sensor prototype. The practical reason for basing the measurement on the application of this thick film sensor is to find out whether the operational integration of the sensor and the circuit has been achieved according to the original hypothesis. Importantly, it is also necessary to determine whether the reproducibility of measured results has been reached. The innovative aspect of the created device consists in the improvement of output characteristics given by the integration of ASIC (IMAM CHIP). The integration of ASIC on the surface of the sensor eliminates the huge parasitic influence that affects the accuracy of measurement.
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The measurements of earthing systems and the role of electrical soil resistivity
Capyk, Jan ; Jurák, Viktor (referee) ; Vyčítal, Václav (advisor)
The theoretical part of the thesis is focused on explaining the concept of soil resistivity, applicable methods of its measurement, comparison of two methods used to measure the resistance of the earth electrode and a description of the measuring device Metro PU 193 used for the practical part of the thesis. In the practical part, the reader is acquainted with the results of measuring soil resistivity and earth resistance in the field, with their evaluation with respect to various influencing factors and with designs of earth conductors for high voltage poles for which soil resistivity was measured. The thesis contains plotted graphs of various dependencies according to the results of measured values and compares them with theoretical assumptions.
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Production of Parts into the Injection Mold
Pilarčík, Edmund ; Jaroš, Aleš (referee) ; Kalivoda, Milan (advisor)
This project processes technology of production of parts into the injection mold in given conditions of ROTEK s.r.o. company, focusing on exploitation of electric discharge machinig. The project consists of constructive – technological analysis of part, proposal of technological procedure suitable for possibilities of the company, simulation of certain manufacturing processes and technological-economic assessment of satisfactory solutions of manufacturing process in company.
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XRD characterization of electrodes and electrode materials for electrochemical power sources
Klvač, Ondřej ; Chladil, Ladislav (referee) ; Čech, Ondřej (advisor)
The thesis describes available choices of methods for research of electrochemical power source electrode strcture by x-ray diffraction spectroscopy. At first there is a theoretical computation of difractogram. Then there are discussed possibilities of in-situ and ex-situ techniques as background research. Practical part of thesis compares theoretical assumptions to measurements of lithium and sodium cells, including analyze of crystallographic phases and lattice constants. As a conclusion, there are discussed possibilities of subsequent research.
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Modification properties of MnOx based positive electrode for AFC
Kamrla, David ; Bača, Petr (referee) ; Novák, Vítězslav (advisor)
The subject of this graduation thesis is low-cost alkaline power cells and especially electrodes with alternative catalyst made of MnOx + dopant. The thesis expands the bachelor´s thesis [1] and previous research [4] [12] [13] [14]. Volt-ampere characteristics and power characteristics of the katodes for AFC, subsidized with various dopants, are the outcome of this project. The project presents the optimalisation of preparation process of AFC electrodes. The aim is to prepair several electrodes with identical construction, which varies only with the type of the dopant.
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Exploring the influence of pressure on the life of lead acid batteries for hybrid electric vehicles
Pospíchal, Martin ; Tošer, Pavel (referee) ; Bača, Petr (advisor)
The lead-acid batteries used in hybrid electronic vehicles HEV operate in high-rate mode in a state of partial charge PSoC. It occurs when the degradation mechanisms related to irreversible sulphation and negative electrodes are a limiting factor in the life of lead-acid batteries. The electrode system was applied to experimental pressure cells of different sizes. Exp. cells were subjected to measurement and evaluation of potential negative electrode, a negative active mass resistance, contact resistance of transition collector - the active mass with the evaluation and measurement of pressure fluctuations within four PSoC runs.
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Methods of ignition spark gaps
Pekárek, Dominik ; Štěpánek, Jaroslav (referee) ; Krbal, Michal (advisor)
This thesis deals with methods of spark gap ignition. The thesis describes spark gap ignition by external electrode, by Rogowski electrode and by lasers. Advantages and disadvantages of these methods are also discussed. In the final part of the thesis there is described experiment with high voltage spark gap.
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Fuel cell and vehicles
Zlámal, Josef ; Kloss, Ondřej (referee) ; Kaplan, Zdeněk (advisor)
In the first part of this work a historical development of fuel cell, description of its construction and function including a comparison of currently used fuel cells is presented. The next part of this work is focused on fuel for fuel cells, its production, distribution and storage. The last chapters are dealing with fuel cell automobile, project of particular car companies and author´s assessment of individual fuel cell systems.
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